Absolute absorption spectroscopy based on molecule interferometry

Author(s)
Stefan Nimmrichter, Klaus Hornberger, Hendrik Ulbricht, Markus Arndt
Abstract

We propose a method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photoinduced fragmentation or ionization. The method is based on resolving the recoil resulting from photon absorption by means of near-field matter-wave interference, and it thus applies even to very dilute beams with low optical densities. Our discussion includes the possibility of internal state conversion as well as fluorescence. We assess the influence of various experimental uncertainties and show that the measurement of absolute absorption cross sections is conceivable with high precision and using existing technologies.

Organisation(s)
Quantum Optics, Quantum Nanophysics and Quantum Information
External organisation(s)
Ludwig-Maximilians-Universität München
Journal
Physical Review A
Volume
78
No. of pages
8
ISSN
1050-2947
DOI
https://doi.org/10.1103/PhysRevA.78.063607
Publication date
2008
Peer reviewed
Yes
Austrian Fields of Science 2012
103026 Quantum optics
Portal url
https://ucrisportal.univie.ac.at/en/publications/35773537-dbc3-4b74-b616-e29673723d25